Palladium hexafluoride

Palladium hexafluoride
Names
Other names Palladium(VI) fluoride
Identifiers
3D model (JSmol)	Interactive image
InChI InChI=1S/6FH.Pd/h6*1H;/q;;;;;;+6/p-6 Key: MHMVGGBINBRGRB-UHFFFAOYSA-H
SMILES F[Pd](F)(F)(F)(F)F
Properties
Chemical formula	F₆Pd
Molar mass	220.41 g·mol⁻¹
Appearance	dark red solid^{[citation needed]}
Related compounds
Related compounds	Platinum hexafluoride, osmium hexafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chemical compound

Palladium hexafluoride is an inorganic chemical compound of palladium metal and fluorine with the chemical formula PdF₆.^[1] It is reported to be a still hypothetical compound.^[2] This is one of many palladium fluorides.

Synthesis

Fluorination of palladium powder with atomic fluoride at 900–1700 Pa.^[3]

Physical properties

Palladium hexafluoride is predicted to be stable.^[4] The compound is reported to form dark red solid that decomposes to PdF₄. Palladium hexafluoride is a very powerful oxidizing agent.^[3]

References

^ "Palladium hexafluoride". Russian Journal of Inorganic Chemistry. 29 (1–6). British Library Lending Division with the cooperation of the Royal Society of Chemistry: 283. 1984. Retrieved 29 March 2023.
^ David, Jorge; Fuentealba, Patricio; Restrepo, Albeiro. "Relativistic effects on the hexafluorides of group 10 metals" (PDF). Retrieved 29 March 2023.
^ ^a ^b Griffith, William P.; Robinson, Stephen D.; Swars, Kurt (29 June 2013). Pd Palladium: Palladium Compounds. Springer Science & Business Media. p. 48. ISBN 978-3-662-09188-3. Retrieved 29 March 2023.
^ Aullón, Gabriel; Alvarez, Santiago (1 April 2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride". Inorganic Chemistry. 46 (7): 2700–2703. doi:10.1021/ic0623819. ISSN 0020-1669. PMID 17326630. Retrieved 29 March 2023.

Binary hexafluorides

Known binary hexafluorides

Chalcogen binary hexafluorides	SF₆ SeF₆ TeF₆ PoF₆
Noble gas binary hexafluorides	XeF₆
Transition metal binary hexafluorides	MoF₆ TcF₆ RuF₆ RhF₆ WF₆ ReF₆ OsF₆ IrF₆ PtF₆
Actinide binary hexafluorides	UF₆ NpF₆ PuF₆

Predicted binary hexafluorides

Noble gas binary hexafluorides	KrF₆ RnF ₆
Transition metal binary hexafluorides	CrF₆ PdF₆ AuF₆
Actinide binary hexafluorides	AmF₆ CmF₆ EsF₆