Barium chloride fluoride

Barium chloride fluoride
Names
Other names
Barium chlorofluoride
Identifiers
CAS Number
  • 13718-55-3
3D model (JSmol)
  • Interactive image
ChemSpider
  • 75508
ECHA InfoCard 100.033.874 Edit this at Wikidata
EC Number
  • 237-277-4
PubChem CID
  • 83685
CompTox Dashboard (EPA)
  • 7065598
InChI
  • InChI=1S/Ba.ClH.FH/h;2*1H/q+2;;/p-2
    Key: RBRFDGCVTRKUEW-UHFFFAOYSA-L
  • [F-].[Cl-].[Ba+2]
Properties
Chemical formula
BaClF
Molar mass 191.78 g·mol−1
Appearance white crystals
Density g/cm3
Solubility in water
Poorly soluble
Structure
Crystal structure
Tetragonal
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Barium chloride fluoride is an inorganic chemical compound of barium, chlorine, and fluorine.[1] Its chemical formula is BaClF.[2][3] The compound naturally occurs as zhangpeishanite mineral of the matlockite group.[4] One of the deposits where the mineral is mined is Bayan Obo in China.[5]

Synthesis

Barium fluoride can be prepared by precipitating barium chloride and ammonium fluoride in a solution.

Physical properties

Barium chloride fluoride forms white crystals.[6] The crystal structure of BaClF is a tetragonal distortion of that of fluoride type BaF
2
.[7]

The compound is poorly soluble in water.[8]

References

  1. ^ Hagemann, H.; D’Anna, V.; Lawson Daku, M.; Kubel, F. (7 March 2012). "Crystal Chemistry in the Barium Fluoride Chloride System". Crystal Growth & Design. 12 (3): 1124–1131. doi:10.1021/cg201588s. ISSN 1528-7483. Retrieved 26 March 2023.
  2. ^ "System of Registries | US EPA". United States Environmental Protection Agency. Retrieved 26 March 2023.
  3. ^ "CAS 13718-55-3 Barium chloride fluoride - Alfa Chemistry". Alfa Chemistry. Retrieved 26 March 2023.
  4. ^ 英彦, 島崎; 律郎, 宮脇; 一己, 横山; 聰, 松原; 主明, 楊 (2007). "中国内モンゴル白雲鄂博産の新鉱物,張培善石". 日本鉱物科学会年会講演要旨集. 2007: 198. doi:10.14824/jakoka.2007.0.198.0. Retrieved 27 March 2023.
  5. ^ "Zhangpeishanite". mindat.org. Retrieved 27 March 2023.
  6. ^ Lide, David R. (19 June 2003). 1998 Freshman Achievement Award. CRC Press. pp. 4–49. ISBN 978-0-8493-0594-8. Retrieved 26 March 2023.
  7. ^ Marcus, Philippe; Maurice, Vincent (25 May 2006). Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers: A Selection of Papers from the 9th International Symposium, Paris, France, 27 June - 1 July 2005. Elsevier. p. 150. ISBN 978-0-08-046152-6. Retrieved 26 March 2023.
  8. ^ Comey, Arthur Messinger (1896). A Dictionary of chemical solubilities. Macmillan and Company. p. 47. Retrieved 26 March 2023.
  • v
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  • BaB6
  • Ba(BO2)2
  • BaBr2
  • Ba(BrO3)2
  • Ba(CH3CO2)2
  • Ba(C5H7O2)2
  • Ba(ClO)2
  • BaC2
  • BaCO3
  • BaC2O4
  • Ba(ClO3)2
  • BaClF
  • Ba(ClO4)2
  • Ba(CN)2
  • BaCl2
  • BaCrO4
  • BaF2
  • BaFeO4
  • BaFe2O4
  • BaH2
  • BaI2
  • Ba(IO3)2
  • BaMnO4
  • Ba(MnO4)2
  • Ba(N3)2
  • Ba(NO2)2
  • Ba(NO3)2
  • BaO
  • BaO2
  • Ba(OH)2
  • Ba(PO3)2
  • BaS
  • BaSe
  • BaSeO4
  • Ba(SCN)2
  • BaSO3
  • BaSO4
  • BaRuO3
  • BaSnO3
  • BaTiO3
  • Ba2TiO4
  • BaWO4
  • BaZnGa
  • Sr2Ba1-xNb2O6
  • YBa2Cu3O7-x
  • v
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  • e
HF He
LiF BeF2 BF
BF3
B2F4
CF4
CxFy
NF3
N2F4
OF
OF2
O2F2
O2F
F Ne
NaF MgF2 AlF
AlF3
SiF4 P2F4
PF3
PF5
S2F2
SF2
S2F4
SF4
S2F10
SF6
ClF
ClF3
ClF5
HArF
ArF2
KF CaF2 ScF3 TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
CrF6
MnF2
MnF3
MnF4
FeF2
FeF3
CoF2
CoF3
NiF2
NiF3
CuF
CuF2
ZnF2 GaF3 GeF4 AsF3
AsF5
SeF4
SeF6
BrF
BrF3
BrF5
KrF2
KrF4
KrF6
RbF SrF2 YF3 ZrF4 NbF4
NbF5
MoF4
MoF5
MoF6
TcF6 RuF3
RuF4
RuF5
RuF6
RhF3
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
PdF6
AgF
AgF2
AgF3
Ag2F
CdF2 InF3 SnF2
SnF4
SbF3
SbF5
TeF4
TeF6
IF
IF3
IF5
IF7
XeF2
XeF4
XeF6
XeF8
CsF BaF2 * LuF3 HfF4 TaF5 WF4
WF6
ReF6
ReF7
OsF4
OsF5
OsF6
OsF
7

OsF8
IrF3
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
AuF5·F2
HgF2
Hg2F2
HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF4
PoF6
At RnF2
RnF6
Fr RaF2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
* LaF3 CeF3
CeF4
PrF3
PrF4
NdF3 PmF3 SmF2
SmF3
EuF2
EuF3
GdF3 TbF3
TbF4
DyF3 HoF3 ErF3 TmF2
TmF3
YbF2
YbF3
** AcF3 ThF4 PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF3
AmF4
AmF6
CmF3 Bk Cf Es Fm Md No
PF6, AsF6, SbF6 compounds
  • AgPF6
  • KAsF6
  • LiAsF6
  • NaAsF6
  • HPF6
  • HSbF6
  • NH4PF6
  • KPF6
  • KSbF6
  • LiPF6
  • NaPF6
  • NaSbF6
  • TlPF6
AlF6 compounds
  • Cs2AlF5
  • K3AlF6
  • Na3AlF6
chlorides, bromides, iodides
and pseudohalogenides
SiF62-, GeF62- compounds
  • BaSiF6
  • BaGeF6
  • (NH4)2SiF6
  • Na2[SiF6]
  • K2[SiF6]
Oxyfluorides
  • BrOF3
  • BrO2F
  • BrO3F
  • LaOF
  • ThOF2
  • VOF
    3
  • TcO
    3
    F
  • WOF
    4
  • YOF
  • ClOF3
  • ClO2F3
Organofluorides
  • CBrF3
  • CBr2F2
  • CBr3F
  • CClF3
  • CCl2F2
  • CCl3F
  • CF2O
  • CF3I
  • CHF3
  • CH2F2
  • CH3F
  • C2Cl3F3
  • C2H3F
  • C6H5F
  • C7H5F3
  • C15F33N
  • C3H5F
  • C6H11F
with transition metal,
lanthanide, actinide, ammonium
  • VOF3
  • CrOF4
  • CrF2O2
  • NH4F
  • (NH4)2ZrF6
  • CsXeF7
  • Li2TiF6
  • Li2ZrF6
  • K2TiF6
  • Rb2TiF6
  • Na2TiF6
  • Na2ZrF6
  • K2NbF7
  • K2TaF7
  • K2ZrF6
  • UO2F2
nitric acids
bifluorides
  • KHF2
  • NaHF2
  • NH4HF2
thionyl, phosphoryl,
and iodosyl
  • F2OS
  • F3OP
  • PSF3
  • IOF3
  • IO3F
  • IOF5
  • IO2F
  • IO2F3
  • v
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Chlorides and acids
  • HCl
  • HClO
  • HClO2
  • HClO3
  • HClO4
  • HSO3Cl
  • BaClF
  • BCl3
  • CCl4
  • SiCl4
  • TiCl4
  • C3H5Cl
Chlorine fluorides
Chlorine oxides
  • ClO
  • ClO2
  • Cl2O
  • Cl2O2
  • Cl2O3
  • Cl2O4
  • Cl2O5
  • Cl2O6
  • Cl2O7
  • ClO4
Chlorine oxyfluorides
  • ClOF
  • ClOF3
  • ClO2F
  • ClOF5 (predicted)
  • ClO2F3
  • ClO3F
Chlorine(I) derivatives
  • ClNO3
  • ClSO3F
  • ClN3
  • Cl3N


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