Neptunium silicide

Neptunium silicide
Names
Other names
Neptunium disilicide
Identifiers
CAS Number
  • 60862-56-8 checkY
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/Np.2Si
    Key: KBXNGDVSIABQJL-UHFFFAOYSA-N
  • [Np].[Si].[Si]
Properties
Chemical formula
NpSi2
Appearance Crystals
Density 9.03
Solubility in water
insoluble
Related compounds
Related compounds
Plutonium silicide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Neptunium silicide is a binary inorganic compound of neptunium and silicon with the chemical formula NpSi
2
.[1] The compound forms crystals and does not dissolve in water.[2]

Synthesis

Heating neptunium trifluoride with powdered silicon in vacuum:[3]

4 N p F 3 + 11 S i   1500 o C   4 N p S i 2 + 3 S i F 4 {\displaystyle {\mathsf {4NpF_{3}+11Si\ \xrightarrow {1500^{o}C} \ 4NpSi_{2}+3SiF_{4}}}}

Physical properties

Neptunium silicide forms crystals[4] of tetragonal crystal system, space group I41/amd, cell parameters: a = 0.396 nm, c = 1.367 nm, Z = 4.[5]

Neptunium disilicide does not dissolve in water.

Chemical properties

Neptunium disilicide reacts with HCl:[3]

N p S i 2 + 8 H C l     N p C l 4 + 2 S i H 4 {\displaystyle {\mathsf {NpSi_{2}+8HCl\ \xrightarrow {\ } NpCl_{4}+2SiH_{4}}}}

References

  1. ^ Donnay, J. D. H.; Nowacki, Werner (1954). Crystal Data: Classification of Substances by Space Groups and their Identification from Cell Dimensions. Geological Society of America. p. 383. ISBN 978-0-8137-1060-0. Retrieved 16 August 2021.
  2. ^ Koch, Günter (5 October 2013). Transurane: Teil C: Die Verbindungen (in German). Springer-Verlag. p. 245. ISBN 978-3-662-11547-3. Retrieved 16 August 2021.
  3. ^ a b Sheft, Irving; Fried, Sherman (1950). New Neptunium Compounds. U.S. Atomic Energy Commission, Technical Information Division. p. 4. Retrieved 16 August 2021.
  4. ^ Zachariasen, William Houlder (1949). The Crystal Structure of Uranium Silicides and of CeSi2, NpSi2, and PuSi2. U.S. Atomic Energy Commission, Technical Information Branch. p. 3. Retrieved 16 August 2021.
  5. ^ "mp-21298: NpSi2 (tetragonal, I4_1/amd, 141)". materialsproject.org. Retrieved 16 August 2021.
  • v
  • t
  • e
Neptunium compounds
Np(III)
  • NpAs
  • NpAs2
  • NpBr3
  • NpF3
  • NpCl3
  • NpI3
  • NpN
  • NpP
  • NpSi2
Np(IV)
  • NpCl4
  • NpBr4
  • NpF4
  • Np(NO3)4
  • NpO2
  • Np3P4
  • NpC
Organoneptunium(IV) compounds
  • Np(C2O4)2
  • Np(C8H8)2
Np(V)
  • NpF5
Np(VI)
  • NpF6
Np(VII)
  • NpO2(OH)3
  • v
  • t
  • e
Si(II)
Si(III)
  • Si2H6
  • Si2Cl6
Si(IV)
  • SiBr4
  • SiC
  • SiCl4
  • SiF4
  • SiH4
  • SiI4
  • SiAu4
  • SiO2
  • SiS2
  • Si3N4
  • Si(N3)4
  • Si2N2O
  • Si2Cl6O
  • SiF3Cl
  • v
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  • e
Salts and covalent derivatives of the silicide ion
SiH4
+H
He
LiSi Be2Si SiB3
SiB6
+B
SiC
+C
Si3N4
-N
+N
SiO2 SiF4 Ne
NaSi Mg2Si Al Si4− SiP, SiP2
-P
+P
SiS2
-S
SiCl4 Ar
KSi CaSi
CaSi2
ScSi Sc5Si3 Sc2Si3 Sc5Si4 TiSi
TiSi2
V3Si V5Si3, V6Si5, VSi2, V6Si5 Cr3Si Cr5Si3, CrSi, CrSi2 MnSi, MnSi2, Mn9Si2, Mn3Si, Mn5Si3, Mn11Si9 FeSi2
FeSi
Fe5Si3
Fe2Si
Fe3Si
CoSi, CoSi2, Co2Si, Co3Si NiSi, more… Cu17Si3, Cu56Si11, Cu5Si, Cu33Si7, Cu4Si, Cu19Si6, Cu3Si, Cu87Si13 Zn Ga GeSi
+Ge
SiAs, SiAs2
-As
+As
SiSe2 SiSe SiBr4 Kr
RbSi SrSi2 YSi Y5Si3, Y5Si4, Y3Si5, YSi1.4 ZrSi Zr5Si3, Zr5Si4, ZrSi2, Zr3Si2, Zr2Si, Zr3Si Nb4Si Nb5Si3 MoSi2
Mo3Si Mo5Si3
Tc RuSi Ru2Si, Ru4Si3, Ru2Si3 RhSi Rh2Si, Rh5Si3, Rh3Si2, Rh20Si13 PdSi Pd5Si, Pd9Si2, Pd3Si, Pd2Si Ag Cd In Sn Sb TeSi2 Te2Si3 SiI4 Xe
CsSi Ba2Si BaSi2, Ba5Si3 Ba3Si4 * Lu5Si3 HfSi Hf2Si, Hf3Si2, Hf5Si4, HfSi2 Ta9Si2, Ta3Si, Ta5Si3 WSi2 W5Si3 ReSi Re2Si, ReSi1.8 Re5Si3 OsSi IrSi PtSi Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaSi2 La5Si3, La3Si2, La5Si4, LaSi CeSi2 Ce5Si3, Ce3Si2, Ce5Si4, CeSi, Ce3Si5 PrSi2 Pr5Si3, Pr3Si2, Pr5Si4, PrSi NdSi Nd5Si3, Nd5Si4, Nd5Si3, Nd3Si4, Nd2Si3, NdSix Pm SmSi2 Sm5Si4, Sm5Si3, SmSi, Sm3Si5 Eu? GdSi2 Gd5Si3, Gd5Si4, GdSi TbSi2 SiTb, Si4Tb5, Si3Tb5 DySi2 DySi HoSi2 Ho5Si3, Ho5Si4, HoSi, Ho4Si5 ErSi2 Er5Si3, Er5Si4, ErSi Tm? YbSi Si1.8Yb, Si5Yb3, Si4Yb3, Si4Yb5, Si3Yb5
** Ac ThSi PaSi USi2 NpSi2 PuSi Am Cm Bk Cf Es Fm Md No