Mimetite

Lead arsenate chloride mineral
(repeating unit)Pb5(AsO4)3ClIMA symbolMim[1]Strunz classification8.BN.05Crystal systemHexagonalCrystal classDipyramidal (6/m)
(same H-M symbol)Space groupP63/mUnit cella = 10.250(2) Å,
c = 7.454(1) Å; Z = 2IdentificationColorPale to bright yellow, yellowish brown, yellow-orange, white, may be colorlessCrystal habitPrismatic to acicular crystals; reniform, botryoidal, globular,TwinningRare on {1122}Cleavage[1011] ImperfectFractureBrittle, conchoidalTenacityBrittleMohs scale hardness3.5–4LusterResinous, subadamantineStreakWhiteDiaphaneityTransparent to translucentSpecific gravity7.1–7.24Optical propertiesUniaxial (−), anomalously biaxialRefractive indexnω = 2.147 nε = 2.128Birefringence0.019PleochroismWeakReferences[2][3][4]

Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής mimetes, meaning "imitator" and refers to mimetite's resemblance to the mineral pyromorphite. This resemblance is not coincidental, as mimetite forms a mineral series with pyromorphite (Pb5(PO4)3Cl) and with vanadinite (Pb5(VO4)3Cl). Notable occurrences are Mapimi, Durango, Mexico and Tsumeb, Namibia.

Properties

Mimetite from Namibia

Mimetite is a lead chloride arsenate mineral with the composition Pb5(AsO4)3Cl. It is a secondary mineral, formed by oxidation of primary lead minerals in arsenic-bearing lead deposits.[2] It typically forms short hexagonal crystals that are yellow to brown to orange in color, very brittle, moderately hard (Mohs hardness 3.5–4), and dense (specific gravity 7.24). It is distinctive for its lack of transparency, its resinous to adamantine luster, and its solubility in nitric acid.[5]

Mimetite forms a complete solid solution series with pyromorphite, with phosphate (PO3−
4) substituting for arsenate (AsO3−
4). The two minerals are almost identical in their properties and can be difficult to distinguish except by laboratory tests. Pyromorphite is the more common mineral at most locales.[5]

Campylite is a name applied to mimetite or pyromorphite that crystallizes as distinctive barrel-shaped crystals forming curved hemispherical aggregates.[5] Bellite is a name formerly applied to a chromium-bearing mimetite, or possibly a mixture of crocoite, mimetite and quartz, which forms attractive orange red crystals, but has been discredited as a distinct mineral species.[6]

Occurrences

Mimetite is found in association with lead and arsenic minerals, including pyromorphite, cerussite, hemimorphite, smithsonite, vanadinite, anglesite, pyrite, mottramite, willemite, and wulfenite.[5][2] Good specimens have been reported from Gila County, Arizona, US; Ojocaliente, Zacatecas, Mexico; Cumberland, England; Johanngeorgenstadt, Saxony, Germany; Namibia; and Broken Hill, Australia.[5]

Mimetite specimen gallery

  • Mimetite from Tsumeb Mine, Namibia
    Mimetite from Tsumeb Mine, Namibia
  • Cluster of translucent, golden mimetite crystals
    Cluster of translucent, golden mimetite crystals
  • Spherical aggregates of botryoidal mimetite
    Spherical aggregates of botryoidal mimetite
  • Mimetite, Pingtouling Mine, Guangdong Province, China. Size: 2.2 x 2.1 x 1.8 cm
    Mimetite, Pingtouling Mine, Guangdong Province, China. Size: 2.2 x 2.1 x 1.8 cm

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). Handbook of Mineralogy (PDF). Chantilly, VA 20151-1110, US: Mineralogical Society of America. Retrieved 12 February 2022.{{cite book}}: CS1 maint: location (link)
  3. ^ Mimetite, Mindat.org, retrieved 12 February 2021
  4. ^ Barthelmy, David (2014). "Mimetite Mineral Data". Mineralogy Database. Webmineral.com. Retrieved 12 February 2022.
  5. ^ a b c d e Sinkankas, John (1964). Mineralogy for amateurs. Princeton, N.J.: Van Nostrand. pp. 419–422. ISBN 0442276249.
  6. ^ Burke, E.A.J. (2006). "A mass discreditation of GQN minerals". The Canadian Mineralogist. 44 (6): 1557–1560. Bibcode:2006CaMin..44.1557B. doi:10.2113/gscanmin.44.6.1557.

External links

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